Catholicism has a very long and important reckoning with the affective potency of materialities, bodies, relics, forms, and flesh. From an anthropological point of view this paper reflects on how emerging positions of the Catholic Church on AI, on its dialogical yet 'dis-embodied' nature, presents important conundrums regarding questions of theodicy (where is the location and accountability of the sin/sinner?) and personhood (as (in)dividuality and its doubling). Catholicism has long been concerned with doubles, humanity as both fallen and divine image, Christ as both God and man, the Eucharist as both bread and body. Doubling is central to Catholic metaphysics. AI introduces a new form of such doubling: it is cast as our reflection (trained on our language, images, patterns) and yet also emerges as other, uncanny, exceeding us. This paper offers some political-theological reflections on the changing and re-envisioning of Catholic personhood since if Catholic social teaching sees AI as a new site of incarnation and rupture, we must also read these developments for their consequences for sovereignty, labor, migration, and the human body itself.